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1

The modern interpretation of the Wittig reaction mechanism

Byrne, Peter A., Gilheany, Declan G.

Journal:

Chemical Society Reviews

Year:

2013

Language:

english

File:

PDF, 2.62 MB

english, 2013

2

A convenient and mild chromatography-free method for the purification of the products of Wittig and Appel reactions

Byrne, Peter A., Rajendran, Kamalraj V., Muldoon, Jimmy, Gilheany, Declan G.

Journal:

Organic & Biomolecular Chemistry

Year:

2012

Language:

english

File:

PDF, 174 KB

english, 2012

3

Asymmetric Grignard Synthesis of Tertiary Alcohols through Rational Ligand Design

Bieszczad, Bartosz, Gilheany, Declan G.

Journal:

Angewandte Chemie

Year:

2017

Language:

english

File:

PDF, 901 KB

english, 2017

4

ChemInform Abstract: Air-Stable Chiral Primary Phosphines. Part 1. Synthesis, Stability and Applications

Rachei M. Hiney, Arne Ficks, Helge Muller-Bunz, Declan G. Gilheany, Lee J. Higham

Journal:

Year:

2012

File:

PDF, 18 KB

2012

5

Chromium catalysed asymmetric alkene epoxidation. greater selectivity for an E-alkene versus its Z-isomer

Claudine Bousquet, Declan G. Gilheany

Journal:

Tetrahedron Letters

Year:

1995

Language:

english

File:

PDF, 307 KB

english, 1995

6

Ylides, phosphoniumNo d Orbitals but Walsh Diagrams and Maybe Banana Bonds: Chemical Bonding in Phosphines, Phosphine Oxides, and Phosphonium Ylides

Gilheany, Declan G.

Journal:

Chemical Reviews

Year:

1994

Language:

english

File:

PDF, 9.05 MB

english, 1994

7

Berichtigung: Asymmetric Grignard Synthesis of Tertiary Alcohols through Rational Ligand Design

Bieszczad, Bartosz, Gilheany, Declan G.

Journal:

Angewandte Chemie

Year:

2017

File:

PDF, 410 KB

2017

8

Chromium–Salen-Mediated Alkene Epoxidation: A Theoretical and Experimental Study Indicates the Importance of Spin-Surface Crossing and the Presence of a Discrete Intermediate

Peter Brandt, Per-Ola Norrby, Adrian M. Daly, Declan G. Gilheany

Journal:

Chemistry - A European Journal

Year:

2002

Language:

english

File:

PDF, 183 KB

english, 2002

9

Taming a Functional Group: Creating Air-Stable, Chiral Primary Phosphanes

Rachel M. Hiney, Lee J. Higham, Helge Müller-Bunz, Declan G. Gilheany

Journal:

Angewandte Chemie

Year:

2006

Language:

english

File:

PDF, 156 KB

english, 2006

10

Taming a Functional Group: Creating Air-Stable, Chiral Primary Phosphanes

Rachel M. Hiney, Lee J. Higham, Helge Müller-Bunz, Declan G. Gilheany

Journal:

Angewandte Chemie International Edition

Year:

2006

Language:

english

File:

PDF, 157 KB

english, 2006

11

ChemInform Abstract: Studies in the Oxidative Ring-Opening of Catechols and o-Benzoquinones. Lead Tetraacetate versus the Copper(I) Chloride/Pyridine/Methanol System.

James G. Walsh, Patrick J. Furlong, Louise A. Byrne, Declan G. Gilheany

Journal:

Year:

2000

File:

PDF, 36 KB

2000

12

ChemInform Abstract: Easy Access to Medium Rings by Entropy/Strain Reduction. Part 2. The Ready Availability of cis,cis-2,4-Diene-1,6-diols and Derived Dibromides Allows a Simple and Mild Route to Substituted 2,7-Dihydro-1H-azepines.

James G. Walsh, Patrick J. Furlong, Declan G. Gilheany

Journal:

Year:

2000

File:

PDF, 35 KB

2000

13

ChemInform Abstract: Easy Access to Medium Rings by Entropy/Strain Reduction. Part 4. A Simple and Mild Route to Some Substituted 2,7-Dihydro-1H-oxepins, Thiepins and a Phosphepin.

James G. Walsh, Declan G. Gilheany

Journal:

Year:

2000

File:

PDF, 30 KB

2000

14

ChemInform Abstract: Asymmetric Alkene Epoxidation with Chromium Oxo Salen Complexes. A Systematic Study of Salen Ligand Substituents.

Colm P. O'Mahony, Eoghan M. McGarrigle, Marie F. Renehan, Kenneth M. Ryan, Nessan J. Kerrigan, Claudine Bousquet, Declan G. Gilheany

Journal:

Year:

2002

File:

PDF, 31 KB

2002

15

The Synthesis and Use in Asymmetric Epoxidation of Metal Salen Complexes Derived from Enantiopure trans-Cyclopentane- and Cyclobutane-1,2-diamine.

Adrian M. Daly, Declan G. Gilheany

Journal:

Year:

2003

File:

PDF, 174 KB

2003

16

Easy Access to Medium Rings by Entropy/Strain Reduction. Part 3. Competition Between Dihydroazepine and Enamine Formation in Reaction of Tetrahalosubstituted Dibromides with Primary Amines.

James G. Walsh, Declan G. Gilheany

Journal:

Year:

2003

File:

PDF, 146 KB

2003

17

Studies in the Preparation of Novel P-Chirogenic Binaphthyl Monophosphanes (MOPs).

Nessan J. Kerrigan, Eoin C. Dunne, Desmond Cunningham, Patrick McArdle, Karen Gilligan, Declan G. Gilheany

Journal:

Year:

2004

File:

PDF, 73 KB

2004

18

A Novel Azulene Synthesis from the Ramirez Ylide Involving Two Different Modes of Its Reaction with Activated Alkynes.

Lee J. Higham, P. Gabriel Kelly, David M. Corr, Helge Mueller-Bunz, Brian J. Walker, Declan G. Gilheany

Journal:

Year:

2004

File:

PDF, 75 KB

2004

19

Simple Syntheses of Seven-Membered Rings via an Entropy/Strain Reduction Strategy

Louise A. Byrne, Declan G. Gilheany

Journal:

Year:

2004

File:

PDF, 57 KB

2004

20

Easy Access to Medium Rings by Entropy/Strain Reduction. Part 5. A Simple and Mild Route to Cyclohepta-1,3-dienes.

Louise A. Byrne, Patrick J. Furlong, Declan G. Gilheany

Journal:

Year:

2004

File:

PDF, 23 KB

2004

21

Chromium— and Manganese—Salen Promoted Epoxidation of Alkenes

Eoghan M. McGarrigle, Declan G. Gilheany

Journal:

Year:

2005

File:

PDF, 8 KB

2005

22

P-Stereogenic Phosphorus Compounds: Effect of Aryl Substituents on the Oxidation of Arylmethylphenylphosphanes under Asymmetric Appel Conditions

Kamalraj V. Rajendran, Lorna Kennedy, Declan G. Gilheany

Journal:

European Journal of Organic Chemistry

Year:

2010

Language:

english

File:

PDF, 309 KB

english, 2010

23

Easy access to medium rings by entropy/strain reduction, Part 3. Competition between dihydroazepine and enamine formation in reaction of tetrahalosubstituted dibromides with primary amines

James G. Walsh, Declan G. Gilheany

Journal:

Journal of Heterocyclic Chemistry

Year:

2002

Language:

english

File:

PDF, 48 KB

english, 2002

24

P-chirogenic phosphines. MOP/diPAMP hybrids, their oxide crystal structures, reduction studies and alternative syntheses

Lee J. Higham, Eoin F. Clarke, Helge Müller-Bunz, Declan G. Gilheany

Journal:

Journal of Organometallic Chemistry

Year:

2005

Language:

english

File:

PDF, 415 KB

english, 2005

25

Studies in the preparation of novel P-chirogenic binaphthyl monophosphanes (MOPs)

Nessan J Kerrigan, Eoin C Dunne, Desmond Cunningham, Patrick McArdle, Karen Gilligan, Declan G Gilheany

Journal:

Tetrahedron Letters

Year:

2003

Language:

english

File:

PDF, 286 KB

english, 2003

26

Studies in the oxidative ring-opening of catechols and o-benzoquinones. Lead tetraacetate versus the copper(I) chloride/pyridine/methanol system

James G Walsh, Patrick J Furlong, Louise A Byrne, Declan G Gilheany

Journal:

Year:

1999

Language:

english

File:

PDF, 1.35 MB

english, 1999

27

A novel bicyclic phosphonium ylide from the reaction of a 1,2-dihydrophosphorin with dimethyl acetylenedicarboxylate.

Declan G. Gilheany, Deirdre A. Kennedy, John F. Malone, Brian J. Walker

Journal:

Tetrahedron Letters

Year:

1985

Language:

english

File:

PDF, 160 KB

english, 1985

28

Cycloheptatrienyl-phosphorus derivatives. An abnormal phosphonium salt hydrolysis.

Declan G. Gilheany, Norris T. Thompson, Brian J. Walker

Journal:

Tetrahedron Letters

Year:

1987

Language:

english

File:

PDF, 136 KB

english, 1987

29

Ligand-based improvement of enantioselectivity in the catalytic asymmetric dihydroxylation of dialkyl substituted olefins

Tomoyuki Shibata, Declan G. Gilheany, Brent K. Blackburn, K.Barry Sharpless

Journal:

Tetrahedron Letters

Year:

1990

Language:

english

File:

PDF, 226 KB

english, 1990

30

Effect of InCl3 on the addition of Grignard reagents to α,β-unsaturated carbonyl compounds

Brian G. Kelly, Declan G. Gilheany

Journal:

Tetrahedron Letters

Year:

2002

Language:

english

File:

PDF, 94 KB

english, 2002

31

Asymmetric alkene epoxidation with chromium oxo salen complexes. Effect of added phosphoryl ligands

Nessan J Kerrigan, Ivan J Langan, Cormac T Dalton, Adrian M Daly, Claudine Bousquet, Declan G Gilheany

Journal:

Tetrahedron Letters

Year:

2002

Language:

english

File:

PDF, 72 KB

english, 2002

32

Co-operative ortho-effects on the Wittig reaction. Interpretation of stereoselectivity in the reaction of ortho-halo-substituted benzaldehydes and benzylidenetriphenylphosphoranes

Eoin C Dunne, Éamonn J Coyne, Peter B Crowley, Declan G Gilheany

Journal:

Tetrahedron Letters

Year:

2002

Language:

english

File:

PDF, 87 KB

english, 2002

33

Chromium salen catalysed asymmetric alkene epoxidation. Influence of substituents at the 3,3′-positions on the salen rings

Kenneth M. Ryan, Claudine Bousquet, Declan G. Gilheany

Journal:

Tetrahedron Letters

Year:

1999

Language:

english

File:

PDF, 261 KB

english, 1999

34

Unsymmetrical salen ligands: Synthesis and use in chromium mediated asymmetric epoxidation

Adrian M. Daly, T. Cormac Dalton, Marie F. Renehan, Declan G. Gilheany

Journal:

Tetrahedron Letters

Year:

1999

Language:

english

File:

PDF, 242 KB

english, 1999

35

The synthesis and use in asymmetric epoxidation of metal salen complexes derived from enantiopure trans-cyclopentane- and cyclobutane-1,2-diamine

Adrian M. Daly, Declan G. Gilheany

Journal:

Tetrahedron: Asymmetry

Year:

2003

Language:

english

File:

PDF, 273 KB

english, 2003

36

Improved resolution methods for (R,R)- and (S,S)-cyclohexane-1,2-diamine and (R)- and (S)-BINOL

Hans-Jörg Schanz, Michael A Linseis, Declan G Gilheany

Journal:

Tetrahedron: Asymmetry

Year:

2003

Language:

english

File:

PDF, 229 KB

english, 2003

37

Asymmetric alkene epoxidation with chromium oxo salen complexes: Effect of π-rich and other types of additives

Cormac T Dalton, Kenneth M Ryan, Ivan J Langan, Éamonn J Coyne, Declan G Gilheany

Journal:

Journal of Molecular Catalysis A: Chemical

Year:

2002

Language:

english

File:

PDF, 120 KB

english, 2002

38

Salen ligands derived from trans-1,2-dimethyl-1,2-cyclohexanediamine: preparation and application in oxo-chromium salen mediated asymmetric epoxidation of alkenes

Nessan J. Kerrigan, Helge Müller-Bunz, Declan G. Gilheany

Journal:

Journal of Molecular Catalysis A: Chemical

Year:

2005

Language:

english

File:

PDF, 216 KB

english, 2005

39

Unsymmetrical chiral salen Schiff base ligands: Synthesis and use in metal-based asymmetric epoxidation reactions

Marie F. Renehan, Hans-Jörg Schanz, Eoghan M. McGarrigle, Cormac T. Dalton, Adrian M. Daly, Declan G. Gilheany

Journal:

Journal of Molecular Catalysis A: Chemical

Year:

2005

Language:

english

File:

PDF, 550 KB

english, 2005

40

Recent progress towards the understanding of metal–salen catalysed asymmetric alkene epoxidation

Cormac T. Dalton, Kenneth M. Ryan, Valerie M. Wall, Claudine Bousquet, Declan G. Gilheany

Journal:

Topics in Catalysis

Year:

1998

Language:

english

File:

PDF, 261 KB

english, 1998

41

A U-Turn in the Asymmetric Appel Reaction: Stereospecific Reduction of Diastereomerically Enriched Alkoxyphosphonium Salts Allows the Asymmetric Synthesis of P-Stereogenic Phosphanes and Phosphane Boranes

Kamalraj V. Rajendran, Jaya S. Kudavalli, Katherine S. Dunne, Declan G. Gilheany

Journal:

European Journal of Organic Chemistry

Year:

2012

Language:

english

File:

PDF, 250 KB

english, 2012

42

Unequivocal Experimental Evidence for a Unified Lithium Salt-Free Wittig Reaction Mechanism for All Phosphonium Ylide Types: Reactions with β-Heteroatom-Substituted Aldehydes Are Consistently Selective for cis -Oxaphosphetane-Derived Products

Byrne, Peter A., Gilheany, Declan G.

Journal:

Journal of the American Chemical Society

Year:

2012

Language:

english

File:

PDF, 593 KB

english, 2012

43

Rhodium-Catalyzed Hydroformylation Using Hindered Phosphine Ligands: An In Situ Study

Eoin Rafter, Declan G. Gilheany, Joost N. H. Reek, Piet W. N. M. van Leeuwen

Journal:

Year:

2010

Language:

english

File:

PDF, 294 KB

english, 2010

44

ChemInform Abstract: Simple Unprecedented Conversion of Phosphine Oxides and Sulfides to Phosphine Boranes Using Sodium Borohydride.

Kamalraj V. Rajendran, Declan G. Gilheany

Journal:

Year:

2012

File:

PDF, 52 KB

2012

45

Synthesis of P-stereogenic BINAP bissulfide analogues

Eoin Rafter, Jimmy Muldoon, Helge Müller Bunz, Declan G. Gilheany

Journal:

Tetrahedron: Asymmetry

Year:

2011

Language:

english

File:

PDF, 684 KB

english, 2011

46

An easy and short preparation of pentachloroacetone by selective dechlorination of hexachloroacetone under Appel conditions

Kamalraj V. Rajendran, Damien J. Carr, Declan G. Gilheany

Journal:

Tetrahedron Letters

Year:

2011

Language:

english

File:

PDF, 223 KB

english, 2011

47

The synthesis of P-stereogenic MOP analogues and their use in rhodium catalysed asymmetric addition

Eoin F. Clarke, Eoin Rafter, Helge Müller-Bunz, Lee J. Higham, Declan G. Gilheany

Journal:

Journal of Organometallic Chemistry

Year:

2011

Language:

english

File:

PDF, 367 KB

english, 2011

48

Chromium− and Manganese−salen Promoted Epoxidation of Alkenes

McGarrigle, Eoghan M., Gilheany, Declan G.

Journal:

Chemical Reviews

Year:

2005

Language:

english

File:

PDF, 596 KB

english, 2005

49

Direct evidence of a multicentre halogen bond: unexpected contraction of the P–XXX–P fragment in triphenylphosphine dihalides

Nikitin, Kirill, Müller-Bunz, Helge, Gilheany, Declan

Journal:

Chemical Communications

Year:

2013

Language:

english

File:

PDF, 1.28 MB

english, 2013

50

MOP-phosphonites: A novel ligand class for asymmetric catalysis

Ficks, Arne, Hiney, Rachel M., Harrington, Ross W., Gilheany, Declan G., Higham, Lee J.

Journal:

Dalton Transactions

Year:

2012

Language:

english

File:

PDF, 928 KB

english, 2012

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